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High-concentration ammonia nitrogen wastewater treatment and recycling technology

2024-03-24 19:52:57

Cutting-edge environmental information sharing

The atmosphere is rich in ammonia, which is a sufficient and necessary condition for frequent haze explosions!

In the winter of 2017, the average concentration of PM2.5 in Beijing-Tianjin-Hebei and surrounding areas was 85 micrograms per cubic meter, of which nitrate, sulfate, and ammonium salts accounted for 19%, 12%, and 11%, respectively, revealing the atmospheric PM2 in Beijing-Tianjin-Hebei. 5 Chemical characteristics have changed significantly, with similar results measured in the winter of 2018. The rapid generation of components such as nitrate, sulfate, and ammonium has boosted the explosive growth of PM2.5. The ammonium salt is mainly produced by the neutralization reaction of ammonia (NH3) with sulfur, nitrogen and other acidic substances; the concentration of ammonia in the atmosphere of Beijing, Tianjin, Hebei and surrounding areas is significantly higher than that of developed countries and regions such as the United States, which is in an ammonia-rich state.

In recent years, the concentration of SO2 in the region has continued to decline, and the concentration of NH3 in the atmosphere has increased without decline, which is more conducive to the formation of nitrates.

 

Part1 Overview of ammonia nitrogen wastewater source and treatment technology

Overview of ammonia nitrogen wastewater source and main treatment technology

The main methods of ammonia nitrogen wastewater treatment:

Biochemical method, inflection point chlorine method, ion exchange method, chemical precipitation method (MAP), membrane method, air stripping method, steam stripping method, etc.


MethodAmmonia nitrogen concentrationProduct / Recycled ProductScope and advantages / disadvantagesIndustry
1Nitrification / Denitrification (Biochemical)Mid LoNitrogen, not recycledSuitable for wastewater with large water volume and low concentration, large investment area and low operating costMunicipal
2Ion exchange methodMid LoAmmonium salt solutionHigh water inlet requirement and good water outlet effectInorganic chemical industry
3Membrane separationMid LoAmmonium salt solutionHigh water inlet requirement and good water outlet effectInorganic chemical industry
4MAP precipitation methodHighMagnesium ammonium phosphateFertilizer can be made, high running costChemical industry
5Inflection point chlorine methodLowNot recycledSimple process and high running costAdvanced processing
6Air strippingMid HighAmmonium salt solutionSecondary pollution, poor effluent effectChemical industry
7Steam strippingHighAmmonia / AmmoniaThe process is complicated, and ammonia can be recycledChemical industry

 

Part2 High-concentration ammonia nitrogen wastewater treatment and resource utilization technology

NH4+-NInorganic ammonia nitrogen in water exists in the state of ammonia ion (NH4 +) and free ammonia (NH3). The equilibrium relationship between the two is as follows:
NH3 + H2O ⇌ NH4 ++ OH-
pH and temperatureThe balance of NH4 + and NH3 in wastewater is greatly affected by pH and temperature. Generally, the higher the pH, the higher the temperature, and the greater the proportion of free ammonia NH3 in the water.
Deamination principleWhen the wastewater is under alkaline conditions, the equilibrium shifts to the left and the proportion of free ammonia increases.
If steam is passed into the wastewater, the free ammonia will be transferred from the wastewater liquid phase to the gas phase with the steam flow, thereby achieving the removal of ammonia nitrogen NH3 · H2O = H2O + NH3 ↑ (high temperature).

 

Schematic diagram of the process of recovering ammonia water by stripping ammonia removal at atmospheric pressure

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Schematic diagram of the process of recovering ammonia water by negative pressure stripping and deamination

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core advantages

(1) High deamination efficiency: high efficiency and precision U-shaped trays: our invention patented technology, U-shaped diversion jet trays with large flux and low resistance drop; greatly improve the separation efficiency of deamination tower; reduce equipment Cost; the one-time discharge standard (≤15mg / L) for the treatment of ammonia nitrogen wastewater, with a minimum of 5mg / L or less.
(2) Low operating cost: The steam consumption is ≤110 kg / ton of water, which can save more than 25% compared with the domestic conventional deamination system.
(3) Large operating flexibility: The processing capacity can be adjusted from 80 to 110%.
(4) Advanced self-control level: visual display of working condition data, automatic one-button switching by hand; automatic operation of real-time tracking, interlocking, adjustment, and recording.
(5) Rich case experience: The technology is mature and reliable, with multiple successful cases, equipment serialization, complete set, modularization, and automation.
(6) Excellent project team: Has an experienced design, installation, commissioning, and after-sales team.

Multiple patents, serialization, complete sets, automation

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装置模型
 

 

Part3 project performance

Typical industries: ternary lithium battery industry, non-ferrous metals, coal chemical industry, pesticides, medicine, glass, chlor-alkali, photovoltaic, etc.

Partial performance list in the past 3 years: glass / photovoltaic / chemical industry

NumberClient's nameIndustryScaleQuantityLocation
1Hebei Dejin Glass Co., Ltd.Float glass300t / day1setHebei · Shahe
2Sichuan Hengtai Environmental Technology Co., Ltd.Photovoltaic energy240t / day1setSichuan Mianyang
3Shanghai Bizhou Environmental Technology Co., Ltd.Photovoltaic energy30t / day1setYangzhou, Jiangsu
4Xuancheng Yabang Chemical Co., Ltd.Chemical pigment1000t / day1setXuancheng, Anhui
5Jilin Cornell Chemical Industry Co., Ltd.Coal chemical industry600t / day1setJilin Jilin
6Lianhua Technology Co., Ltd.Chemical Pharmaceutical30t / day1setTaizhou, Zhejiang
7Hubei Yuanda Life Science and Technology Co., Ltd.Chemical Medicine150t / day1setHuangshi, Hubei
8China Catalyst New Materials Co., Ltd.Catalyst120t / day1setDalian, Liaoning
9Shandong Wendeng Xijiao Thermal Power Co., Ltd.Chlor-Alkali Chemical840t / day1setShandong Wendeng
10Wuxi Fortune Pharmaceutical Co., Ltd.Chemical Pharmaceutical300t / day1setJiangsu Wuxi

 

List of partial performance in the past 3 years: ternary precursor cathode materials industry for power lithium batteries

NumberClient's nameIndustryScaleQuantityLocation
1New Times Group Zhejiang Energy New Materials Co., Ltd.Ternary cathode material for lithium batteryPhase I500t / day Phase II 1000t / day2 setsShangyu, Zhejiang
2Guangdong Fangyuan Environmental Co., Ltd.Ternary cathode material for lithium battery600t / day1setJiangmen, Guangdong
3Henan Kelong New Energy Co., Ltd.Ternary cathode material for lithium batteryPhase I500t / day Phase II 1300t / day2setsXinxiang, Henan
4Polyfluorochemical co., Ltd.Ternary cathode material for lithium battery30t / day1setJiaozuo, Henan
5Jiangxi Ganfeng Lithium Industry Co., Ltd.Ternary cathode material for lithium battery300t / day1setJiangxi · Xinyu
6Yuyao Fengyuan Power Supply Co., Ltd.Ternary cathode material for lithium battery300t / day1setShaoxing, Zhejiang
7Meishan Shunying Power Battery Material Co., Ltd.Ternary cathode material for lithium battery100t / day1setSichuan · Meishan
8Chizhou Xinen New Material Technology Co., Ltd.Ternary cathode material for lithium battery300t / day1setChizhou, Anhui
9Hunan Jinfuli New Material Co., Ltd.Ternary cathode material for lithium battery300t / day1setChangsha, Hunan

 

UnitXuancheng Yabang Chemical5.jpg
Scale1200 tons / day ammonia nitrogen wastewater
WaterAmmonia nitrogen concentration is about 7000mg / L
EffluentAmmonia nitrogen≤15mg/L
Recycle≥20% ammonia
IndustryChemical Industry (Pigment)

 


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